go to top scroll for more

Projects


Projects: Projects for Investigator
Reference Number EP/M029867/1
Title Recycling of rare earths with ionic liquid solvents: Bridging the gap between molecular modelling and process design
Status Completed
Energy Categories Nuclear Fission and Fusion(Nuclear Fission, Other nuclear fission) 1%;
Renewable Energy Sources(Wind Energy) 3%;
Not Energy Related 96%;
Research Types Basic and strategic applied research 100%
Science and Technology Fields ENGINEERING AND TECHNOLOGY (Chemical Engineering) 100%
UKERC Cross Cutting Characterisation Not Cross-cutting 100%
Principal Investigator Professor AJ Masters
No email address given
Chemical Engineering and Analytical Science
University of Manchester
Award Type Standard
Funding Source EPSRC
Start Date 01 September 2015
End Date 31 August 2018
Duration 36 months
Total Grant Value £599,506
Industrial Sectors Chemicals
Region North West
Programme NC : Engineering, NC : Physical Sciences
 
Investigators Principal Investigator Professor AJ Masters , Chemical Engineering and Analytical Science, University of Manchester (99.998%)
  Other Investigator Dr M Jobson , Chemical Engineering and Analytical Science, University of Manchester (0.001%)
Dr M Gonzalez-Miquel , Chemical Engineering and Analytical Science, University of Manchester (0.001%)
  Industrial Collaborator Project Contact , Katholieke Universiteit Leuven (KU Leuven), Belgium (0.000%)
Web Site
Objectives
Abstract While rare earth metals are used in relatively small quantities, they play a major role in cutting edge technologies, such as electronics, information technology and in automobile industries. These metals are used in the high-powered magnets used in computers, they are components of wind-turbines and electric cars, they are used in fluorescent lights and in several catalytic processes. Roughly 86% of all rare earths come from China. This has been recognised as a significant risk to be so dependent on one country. Unfortunately the UK possesses very few rare-earth containing minerals, but what it can do to become more self-sufficient is to recycle the rare-earths that are in waste-piles. Currently the UK has little activity in this area, but recent parliamentary reports draw attention to the need for protecting the supply of rare earths and one foresees a growing effort in this area.The UK does possess, however, a strong scientific base in the reprocessing of nuclear fuel using liquid-liquid extraction. We have worked in this area, alongside the National Nuclear laboratory. The knowledge gathered from these activities can usefully be re-chanelled into designing efficient extraction methodologies for the chemically-related rare earths. This is our intention. We will focus on the extraction of the rare-earth, Samarium, from waste high-powered magnets using ionic liquids as extractants. Our aim to to scale-up the chemical processes currently investigated by the Binnemans group in Leuven, Belgium. While we believe our general methodology can usefully be applied to many, disparate processes, our focus will be on three systems. Our proposal is firstly to study these systems at a molecular level, using molecular dynamics simulations, to understand the molecular structures that form during the extraction process. Secondly we shall use these insights to construct soundly based, reliable thermodynamic models so that we can predict system properties over a range of temperatures and compositions. Thirdly we will simulate and evaluate an industrial-scale extraction process, incorporating these models. Finally, one the basis of these models, we will liaise with the Binnemans group so that yet more optimised ionic liquids can be synthesised for rare earth extractions
Publications (none)
Final Report (none)
Added to Database 30/11/15